Question 1

Predict the splitting of each of the numbered hydrogen atoms in the structure below in a S1U1P11S1S1P0H NMR spectrum. Identify as singlet, doublet, triplet, quartet, quintet, sextet, septet, .... Place the correct splitting in the blank to the left of the number. 
-______ 1

Accepted Answer

The answer of Predict the splitting of each of the...

Question 2

Which C4H9Br compound(s)  gives a 13C NMR spectrum consisting of two signals? 4H9Br compound(s)  gives a 13C NMR spectrum consisting of two signals?   A) only 1 B) only 2 C) only 2 and 3 D) 1, 2, 3 and 4" class="answers-bank-image d-inline" rel="preload" >

Accepted Answer

A)  only 1
B)  only 2
C)  only 2 and 3
D)  1, 2, 3 and 4E) B) and C)
F) A) and C)

Question 3

Identify the compound (C8H10) that gives the following 1H NMR spectrum.

Accepted Answer

m-xylene (...

Question 4

How many signals appear in proton-decoupled 13C NMR spectrum of 3,4-dimethylhexane?

Accepted Answer

A)  3
B)  4
C)  5
D)  6E) A) and D)
F) B) and C)

Question 5

How many signals appear in the proton-decoupled 13C NMR spectrum of 3-bromotoluene?

Accepted Answer

A)  3
B)  4
C)  5
D)  7E) A) and B)
F) C) and D)

Question 6

MATCHING
The following questions pertain to the display of NMR spectra. Match a term to each description below.
-The exact place on the spectrum at which a nucleus absorbs is called its _____.

Accepted Answer

A)  TMS
B)  high-field or upfield side
C)  MHz
D)  delta ( δ\deltaδ ) 
E)  low-field or downfield sideF) chemical shiftG) intensity H) B) and C)
I) B) and E)

Question 7

Which C6H12O2 compound gives the following 1H NMR spectrum? 6H12O2 compound gives the following 1H NMR spectrum?   A) 1 B) 2 C) 3 D) 4" class="answers-bank-image d-inline" rel="preload" >

Accepted Answer

A)  1
B)  2
C)  3
D)  4E) All of the above
F) C) and D)

Question 8

Which of the following is true for pair of homotropic protons?
1) They will appear at the same chemical shift in an achiral (i.e., nonchiral)  environment
2) They will appear at the same chemical shifts in a chiral environment

Accepted Answer

A)  only 1
B)  only 2
C)  neither 1 nor 2
D)  both 1 and 2E) B) and C)
F) All of the above

Question 9

Which of the following combinations of peaks appears in the 1H NMR spectrum of diethyl ether, CH3CH2OCH2CH3?

Accepted Answer

A)  a triplet and a doublet
B)  a quartet and a sextet
C)  two singlets
D)  a triplet and a quartetE) All of the above
F) A) and B)

Question 10

How many sets of equivalent protons are there in hexane?

Accepted Answer

A)  2
B)  3
C)  6
D)  7E) B) and C)
F) A) and D)

Question 11

Which of the following combinations of peaks appears in the 1H NMR spectrum of butane?

Accepted Answer

A)  a triplet and a doublet
B)  a triplet and a quartet
C)  a triplet and a sextet
D)  two singletsE) A) and D)
F) A) and C)

Question 12

Which C8H10 compound gives the following 1H NMR spectrum? 8H10 compound gives the following 1H NMR spectrum?   A) 1 B) 2 C) 3 D) 4" class="answers-bank-image d-inline" rel="preload" >

Accepted Answer

A)  1
B)  2
C)  3
D)  4E) All of the above
F) B) and C)

Question 13

Which C4H9Br compound(s)  gives a 13C NMR spectrum consisting of four signals? 4H9Br compound(s)  gives a 13C NMR spectrum consisting of four signals?   A) only 1 B) only 1 and 2 C) only 2 and 3 D) 1, 2, 3 and 4" class="answers-bank-image d-inline" rel="preload" >

Accepted Answer

A)  only 1
B)  only 1 and 2
C)  only 2 and 3
D)  1, 2, 3 and 4E) C) and D)
F) B) and D)

Question 14

Which of the following combinations of peaks appears in the 1H NMR spectrum of 2,3-dimethylbutane?

Accepted Answer

A)  two doublets
B)  a doublet and a septet
C)  a singlet and two doublets
D)  a doublet and an octetE) A) and D)
F) A) and C)

Question 15

Which of the carbon atoms in the following molecule appears furthest downfield in the 13C NMR spectrum? 13C NMR spectrum?   A) i B) ii C) iii D) iv" class="answers-bank-image d-inline" rel="preload" >

Accepted Answer

A)  i
B)  ii
C)  iii
D)  ivE) B) and C)
F) A) and B)

Question 16

Which C8H10 compound gives the following 1H NMR spectrum? 8H10 compound gives the following 1H NMR spectrum?   A) 1 B) 2 C) 3 D) 4" class="answers-bank-image d-inline" rel="preload" >

Accepted Answer

A)  1
B)  2
C)  3
D)  4E) A) and D)
F) B) and C)

Question 17

Which feature in the 1H NMR spectrum provides information about the electronic environment of the protons in a compound?

Accepted Answer

A)  number of signals
B)  integral
C)  splitting
D)  chemical shiftE) A) and B)
F) None of the above

Question 18

What is the splitting of the signal in the 1H NMR spectrum for the methyl protons of ethane?

Accepted Answer

A)  singlet
B)  doublet
C)  triplet
D)  quartetE) B) and C)
F) C) and D)

Question 19

What is the splitting of the signal in the 1H NMR spectrum for the methyl protons of propane?

Accepted Answer

A)  singlet
B)  doublet
C)  triplet
D)  quartetE) A) and D)
F) A) and C)

Question 20

Which of the following compounds gives a 1H NMR spectrum consisting of only a singlet?

Accepted Answer

A)  1,1-dibromopropane
B)  1,2-dibromopropane
C)  1,3-dibromopropane
D)  2,2-dibromopropaneE) All of the above
F) A) and B)

Exam 13: Nuclear Magnetic Resonance Spectroscopy

Predict the splitting of each of the numbered hydrogen atoms in the structure below in a 1H NMR spectrum. Identify as singlet, doublet, triplet, quartet, quintet, sextet, septet, .... Place the correct splitting in the blank to the left of the number. -______ 1

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Which of the following compounds gives a 1H NMR spectrum consisting of only a singlet?

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Which of the following combinations of peaks appears in the 1H NMR spectrum of 2,3-dimethylbutane?

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How many sets of equivalent protons are there in hexane?

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MATCHING The following questions pertain to the display of NMR spectra. Match a term to each description below. -The exact place on the spectrum at which a nucleus absorbs is called its _____.

Correct AnswerverifiedShow Answer

What is the splitting of the signal in the 1H NMR spectrum for the methyl protons of propane?

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Which of the following combinations of peaks appears in the 1H NMR spectrum of butane?

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Identify the compound (C8H10) that gives the following 1H NMR spectrum.

Correct Answerverifiedm-xylene (...View AnswerShow Answer

Which of the following is true for pair of homotropic protons? 1) They will appear at the same chemical shift in an achiral (i.e., nonchiral) environment 2) They will appear at the same chemical shifts in a chiral environment

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Which feature in the 1H NMR spectrum provides information about the electronic environment of the protons in a compound?

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Which C4H9Br compound(s) gives a 13C NMR spectrum consisting of two signals?

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Which of the carbon atoms in the following molecule appears furthest downfield in the 13C NMR spectrum?

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How many signals appear in the proton-decoupled 13C NMR spectrum of 3-bromotoluene?

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What is the splitting of the signal in the 1H NMR spectrum for the methyl protons of ethane?

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Which C6H12O2 compound gives the following 1H NMR spectrum?

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Which of the following combinations of peaks appears in the 1H NMR spectrum of diethyl ether, CH3CH2OCH2CH3?

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How many signals appear in proton-decoupled 13C NMR spectrum of 3,4-dimethylhexane?

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Which C8H10 compound gives the following 1H NMR spectrum?

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Which C4H9Br compound(s) gives a 13C NMR spectrum consisting of four signals?

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Which C8H10 compound gives the following 1H NMR spectrum?

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Predict the splitting of each of the numbered hydrogen atoms in the structure below in a ¹H NMR spectrum. Identify as singlet, doublet, triplet, quartet, quintet, sextet, septet, .... Place the correct splitting in the blank to the left of the number. -______ 1

Correct Answer
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Which of the following compounds gives a ¹H NMR spectrum consisting of only a singlet?

Correct Answer
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Which of the following combinations of peaks appears in the ¹H NMR spectrum of 2,3-dimethylbutane?

Correct Answer
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Correct Answer
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What is the splitting of the signal in the ¹H NMR spectrum for the methyl protons of propane?

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Which of the following combinations of peaks appears in the ¹H NMR spectrum of butane?

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Identify the compound (C₈H₁₀) that gives the following ¹H NMR spectrum.

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m-xylene (...
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Which feature in the ¹H NMR spectrum provides information about the electronic environment of the protons in a compound?

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Which C₄H₉Br compound(s) gives a ¹³C NMR spectrum consisting of two signals?

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Which of the carbon atoms in the following molecule appears furthest downfield in the ¹³C NMR spectrum?

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How many signals appear in the proton-decoupled ¹³C NMR spectrum of 3-bromotoluene?

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What is the splitting of the signal in the ¹H NMR spectrum for the methyl protons of ethane?

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Which C₆H₁₂O₂ compound gives the following ¹H NMR spectrum?

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Which of the following combinations of peaks appears in the ¹H NMR spectrum of diethyl ether, CH₃CH₂OCH₂CH₃?

Correct Answer
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How many signals appear in proton-decoupled ¹³C NMR spectrum of 3,4-dimethylhexane?

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Which C₈H₁₀ compound gives the following ¹H NMR spectrum?

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Which C₄H₉Br compound(s) gives a ¹³C NMR spectrum consisting of four signals?

Correct Answer
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Which C₈H₁₀ compound gives the following ¹H NMR spectrum?

Correct Answer
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