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Which of the following compounds has the lowest pKa?


A) H2O
B) HBr
C) NH3
D) CH4

E) All of the above
F) None of the above

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Which of the following compounds is the strongest acid?


A) CH3COOH
B) FCH2COOH
C) ClCH2COOH
D) BrCH2COOH

E) A) and B)
F) C) and D)

Correct Answer

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Which of the following is easiest to deprotonate?


A) CH4
B) CH3CH3
C) CH2=CH2
D) HC \equiv CH

E) A) and B)
F) None of the above

Correct Answer

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Which of the following compounds has the lowest pKa?


A) H2O
B) H2S
C) H2Se
D) H2Te

E) All of the above
F) A) and C)

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Which of the following compounds has the highest pKa?


A) SiH4
B) H2S
C) PH3
D) HCl

E) B) and C)
F) All of the above

Correct Answer

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Which of the following is the strongest acid?


A) CH3CH3
B) CH3NH2
C) CH3OH
D) CH3F

E) A) and C)
F) A) and B)

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A species that lies at an energy maximum during an individual step in a reaction is termed ____________________.

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Under which of the following conditions will a reaction be spontaneous when Δ\Delta H \circ > 0?


A) "T Δ\Delta S \circ = 0"
B) "T Δ\Delta S \circ > Δ\Delta H \circ "
C) "T Δ\Delta S \circ < 0 \circ "
D) " Δ\Delta G \circ = 0"

E) B) and C)
F) A) and B)

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Complete the equation below for the protonation of 2-butene with HBr. Show the movement of pairs of electrons with curved arrows and provide the structures of the conjugate acid and conjugate base. Complete the equation below for the protonation of 2-butene with HBr. Show the movement of pairs of electrons with curved arrows and provide the structures of the conjugate acid and conjugate base.

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Use curved arrows to show the movement of pairs of electrons in the following acid-base reaction and show the structures of the conjugate acid and conjugate base. Use curved arrows to show the movement of pairs of electrons in the following acid-base reaction and show the structures of the conjugate acid and conjugate base.

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What is the approximate pKa value of acetic acid?


A) -7
B) 5
C) 16
D) 51

E) A) and C)
F) A) and D)

Correct Answer

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Indole is pleasant smelling in highly dilute solutions and has been used in perfumery. Indole is pleasant smelling in highly dilute solutions and has been used in perfumery.   Indole can be classified as a Brønsted-Lowry base but not as a Lewis base.. Indole can be classified as a Brønsted-Lowry base but not as a Lewis base..

A) True
B) False

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Which acid has the strongest conjugate base?

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What is the approximate pKa value of HCl?


A) -7
B) 5
C) 16
D) 51

E) All of the above
F) A) and D)

Correct Answer

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What is the value of the equilibrium constant, Keq, for the following reaction? What is the value of the equilibrium constant, K<sub>eq</sub>, for the following reaction?   A)  10<sup>13</sup>  B)  10<sup>-</sup><sup>13</sup>  C)  13  D)  <sup>1</sup>/<sub>13</sub>


A) "1013"
B) "10-13"
C) "13"
D) "1/13"

E) A) and C)
F) None of the above

Correct Answer

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Which of the following is the strongest acid?


A) CH3OH
B) CH3CHO
C) CH3COCH3
D) CH3COOH

E) None of the above
F) B) and D)

Correct Answer

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Provide the equation that relates the equilibrium constant, Keq, to the acid dissociation constant, Ka, for the following equilibrium. Provide the equation that relates the equilibrium constant, K<sub>eq</sub>, to the acid dissociation constant, K<sub>a</sub>, for the following equilibrium.

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In the following list, there are four Lewis acids, CH3OH, HCl, BCl3 and FeBr3. In the following list, there are four Lewis acids, CH<sub>3</sub>OH, HCl, BCl<sub>3</sub> and FeBr<sub>3</sub>.

A) True
B) False

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Which acid will be almost completely deprotonated by NaOH?

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Which of the following compounds is the strongest acid?


A) CH4
B) CH3CH3
C) H2C=CH2
D) HC \equiv CH

E) B) and C)
F) A) and D)

Correct Answer

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