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Exam 8: Haloalkanes, Halogenation, and Radical Reactions

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Question 41

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Which of the following alkenes undergoes allylic bromination to form a single monobrominated product?

A) 1
B) 2
C) 3
D) 4

E) B) and C)
F) A) and D)

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Question 42

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What is the structure of all of the monobrominated products, including regioismers and stereoisomers, obtained from the following reaction?

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Question 43

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The number of possible monobromination products of cyclopentane is______.

Consider the reaction below to answer the following question(s). $\begin{array}{ccccc}\mathrm{CH}_{3} \mathrm{CH}=\mathrm{CHCH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{3}&\underset{h v}{\stackrel{\text { NBS }}{\rightarrow}} &\mathrm{CH}_{3} \mathrm{CH}=\mathrm{CHCHCH}_{2} \mathrm{CH}_{3}&+&\mathrm{CH}_{3} \mathrm{CHCH}=\mathrm{CHCH}_{2} \mathrm{CH}_{3}\\&&|&&|\\&&\mathrm{Br}&&\mathrm{Br}\\A&&B&&C\end{array}$ -The number of allylic positions in compound A is ______.

Which of the following statements is not true about the allyl radical

Provide the IUPAC name of the following compound (shown as a Fischer projection).

What is the characteristic of a radical chain termination step?

What type of reactive intermediate is formed upon irradiation of a solution of toluene (Ph-CH₃) and bromine?

What type of orbitals overlap to provide stability to the tert-butyl radical by hyperconjugation?

The major products of the reaction would be formed from the radical intermediate numbered _____ as shown below. 1. $\mathrm{CH}_{3} \mathrm{CH}=\mathrm{CH}-\dot{\mathrm{C}} \mathrm{HCH}_{2} \mathrm{CH}_{3}$ $\mathrm{CH}_{3} \dot{\mathrm{C}} \mathrm{H}-\mathrm{CH}=\mathrm{CHCH}_{2} \mathrm{CH}_{3}$ 2. $\dot{\mathrm{C}} \mathrm{H}_{2} \mathrm{CH}=\mathrm{CHCH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{3}$ 11ee515b_68f3_8e8d_b56e_e79049de47c8_TB7078_11 $\mathrm{CH}_{2}=\mathrm{CHC} \dot{\mathrm{C}} \mathrm{HCH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{3}$

What is the characteristic of a radical chain propagation step?

Which of the following has the list of compounds in the correct order of decreasing molecular polar (more polar > less polar) ?

Which of the following statements is not true regarding the halogenation of alkanes upon treatment with halogen and light?

What is the characteristic of a radical chain initiation step?

What is the major organic product obtained from the following reaction?